Potential application of 2D nano-layered MXene in analysing and remediating endocrine disruptor compounds and heavy metals in water.

With the advancement of technologies and growth of the economy, it is inevitable that more complex processes are deployed, producing more heterogeneous wastewater that comes from biomedical, biochemical and various biotechnological industries. While the conventional way of wastewater treatment could effectively reduce the chemical oxygen demand, pH and turbidity of wastewater, trace pollutants, specifically the endocrine disruptor compounds (EDCs) that exist in µg L-1 or ng L-1 have further hardened the detection and removal of these biochemical pollutants. Even in small amounts, EDC could interfere human's hormone, causing severe implications on human body. Hence, this review elucidates the recent insights regarding the effectiveness of an advanced 2D material based on titanium carbide (Ti3C2Tx), also known as MXene, in detecting and removing EDCs. MXene's highly tunable feature also allows its surface chemistry to be adjusted by adding chemicals with different functional groups to adsorb different kinds of EDCs for biochemical pollution mitigation. At the same time, the incorporation of MXene into sample matrices also further eases the analysis of trace pollutants down to ng L-1 levels, thereby making way for a more cleaner and comprehensive wastewater treatment. In that sense, this review also highlights the progress in synthesizing MXene from the conventional method to the more modern approaches, together with their respective key parameters. To further understand and attest to the efficacy of MXene, the limitations and current gaps of this potential agent are also accentuated, targeting to seek resolutions for a more sustainable application.

Ionic Liquids Hybridization for Carbon Dioxide Capture: A Review.

CO2 absorption has been driven by the need for efficient and environmentally sustainable CO2 capture technologies. The development in the synthesis of ionic liquids (ILs) has attracted immense attention due to the possibility of obtaining compounds with designated properties. This allows ILs to be used in various applications including, but not limited to, biomass pretreatment, catalysis, additive in lubricants and dye-sensitive solar cell (DSSC). The utilization of ILs to capture carbon dioxide (CO2) is one of the most well-known processes in an effort to improve the quality of natural gas and to reduce the green gases emission. One of the key advantages of ILs relies on their low vapor pressure and high thermal stability properties. Unlike any other traditional solvents, ILs exhibit high solubility and selectivity towards CO2. Frequently studied ILs for CO2 absorption include imidazolium-based ILs such as [HMIM][Tf2N] and [BMIM][OAc], as well as ILs containing amine groups such as [Cho][Gly] and [C1ImPA][Gly]. Though ILs are being considered as alternative solvents for CO2 capture, their full potential is limited by their main drawback, namely, high viscosity. Therefore, the hybridization of ILs has been introduced as a means of optimizing the performance of ILs, given their promising potential in capturing CO2. The resulting hybrid materials are expected to exhibit various ranges of chemical and physical characteristics. This review presents the works on the hybridization of ILs with numerous materials including activated carbon (AC), cellulose, metal-organic framework (MOF) and commercial amines. The primary focus of this review is to present the latest innovative solutions aimed at tackling the challenges associated with IL viscosity and to explore the influences of ILs hybridization toward CO2 capture. In addition, the development and performance of ILs for CO2 capture were explored and discussed. Lastly, the challenges in ILs hybridization were also being addressed.

Synthesis and characterization of ammonium-based protic ionic liquids for carbon dioxide absorption.

A series of ammonium-based protic ionic liquids (APILs) namely ethanolammonium pentanoate [ETOHA][C5], ethanolammonium heptanoate [ETOHA][C7], triethanolammonium pentanoate [TRIETOHA][C5], triethanolammonium heptanoate [TRIETOHA][C7], tributylammonium pentanoate [TBA][C5] and tributylammonium heptanoate [TBA][C7] was synthesized via proton transfer. Their structural confirmation and physiochemical properties namely thermal stability, phase transition, density, heat capacity (Cp) and refractive index (RI) have been determined. Specifically, [TRIETOHA] APILs have crystallization peaks ranging from -31.67 to -1.00 °C, owing to their large density values. A comparison study revealed the low Cp values of APILs in comparison to monoethanolamine (MEA) which could be advantageous for APILs to be used in CO2 separation during recyclability processes. Additionally, the performance of APILs toward CO2 absorption was investigated by using a pressure drop technique under a pressure range of 1-20 bar at 298.15 K. It was observed that [TBA][C7] recorded the highest CO2 absorption capacity with the value of 0.74 mole fraction at 20 bar. Additionally, the regeneration of [TBA][C7] for CO2 absorption was studied. Analysis of the measured CO2 absorption data showed marginal reduction in the mole fraction of CO2 absorbed between fresh and recycled [TBA][C7] thus proving the promising potential of APILs as good liquid absorbents for CO2 removal.

Thermal Kinetics of Monocationic and Dicationic Pyrrolidinium-Based Ionic Liquids.

This work presents an in-depth kinetic thermal degradation comparison between traditional monocationic and the newly developed dicationic ionic liquid (IL), both coupled with a bromide (Br-) anion by using non-isothermal thermogravimetric analysis. Thermal analyses of 1-butyl-1-methylpyrrolidinium bromide [C4MPyr][Br] and 1,4-bis(1-methylpyrrolidinium-1-yl)butane dibromide [BisC4MPyr][Br2] were conducted at a temperature range of 50-650 °C and subjected to various heating rates, which are 5, 10, 15, 20 and 25 °C/min. Thermogravimetric analysis revealed that dicationic IL, [BisC4MPyr][Br2] is less thermally stable compared to monocationic [C4MPyr][Br]. A detailed analysis of kinetic parameters, which are the activation energy (Ea) and pre-exponential factor (log A), was calculated by using Kissinger-Akahira-Sunose (KAS), Flynn-Wall-Ozawa (FWO) and Starink. This study revealed that the average Ea and log A of [BisC4MPyr][Br2] are lower than [C4MPyr][Br], which may be contributed to by its low thermal stability. Conclusively, it proved that the Ea and log A of ILs are strongly related to the thermal stability of ILs.

Correlating black soldier fly larvae growths with soluble nutrients derived from thermally pre-treated waste activated sludge.

Black soldier fly larvae (BSFL) have been deployed to valorize various organic wastes. Nonetheless, its growth rate whilst being offered with waste activated sludge (WAS) is not promising, likely by virtue of the presence of extracellular polymeric substances' structure in WAS. In this work, the WAS were first thermally pre-treated under different treatment temperatures and durations before being administered as the feeding substrates for BSFL. The results showed the thermal pre-treatment could improve WAS palatability and subsequently, enhance the growth of BSFL especially after the pre-treatments at 75 °C and above. The highest larva weight gained was recorded at 2.16 mg/larva for the WAS sample being pre-treated at 90 °C and 16 h. Furthermore, the samples pre-treated above 75 °C also achieved higher degradation rates, indicating that the 75 °C was a threshold temperature to effectively hydrolyze the WAS. The changes of WAS characteristics, namely, (i) soluble chemical oxygen demand (SCOD), (ii) soluble carbohydrate, (iii) soluble protein, (iv) humic substances and (v) total soluble protein and humic substances, after the thermal pre-treatments were also studied in correlating with the BSFL growth. Accordingly, a model was successfully developed with the highest R2 value attained at 0.95, evidencing the SCOD was the most suitable WAS characteristic to accurately predict the BSFL growth behavior.

Experimental Investigation on Thermophysical Properties of Ammonium-Based Protic Ionic Liquids and Their Potential Ability towards CO2 Capture.

Ionic liquids, which are extensively known as low-melting-point salts, have received significant attention as the promising solvent for CO2 capture. This work presents the synthesis, thermophysical properties and the CO2 absorption of a series of ammonium cations coupled with carboxylate anions producing ammonium-based protic ionic liquids (PILs), namely 2-ethylhexylammonium pentanoate ([EHA][C5]), 2-ethylhexylammonium hexanoate ([EHA][C6]), 2-ethylhexylammonium heptanoate ([EHA][C7]), bis-(2-ethylhexyl)ammonium pentanoate ([BEHA][C5]), bis-(2-ethylhexyl)ammonium hexanoate ([BEHA][C6]) and bis-(2-ethylhexyl)ammonium heptanoate ([BEHA][C7]). The chemical structures of the PILs were confirmed by using Nuclear Magnetic Resonance (NMR) spectroscopy while the density (ρ) and the dynamic viscosity (η) of the PILs were determined and analyzed in a range from 293.15K up to 363.15K. The refractive index (nD) was also measured at T = (293.15 to 333.15) K. Thermal analyses conducted via a thermogravimetric analyzer (TGA) and differential scanning calorimeter (DSC) indicated that all PILs have the thermal decomposition temperature, Td of greater than 416K and the presence of glass transition, Tg was detected in each PIL. The CO2 absorption of the PILs was studied up to 29 bar at 298.15 K and the experimental results showed that [BEHA][C7] had the highest CO2 absorption with 0.78 mol at 29 bar. The CO2 absorption values increase in the order of [C5] < [C6] < [C7] anion regardless of the nature of the cation.

A review on recent disposal of hazardous sewage sludge via anaerobic digestion and novel composting.

The high investment cost required by modern treatment technologies of hazardous sewage sludge such as incineration and anaerobic digestion have discouraged their application by many developing countries. Hence, this review elucidates the status, performances and limitations of two low-cost methods for biological treatment of hazardous sewage sludge, employing vermicomposting and black soldier fly larvae (BSFL). Their performances in terms of carbon recovery, nitrogen recovery, mass reduction, pathogen destruction and heavy metal stabilization were assessed alongside with the mature anaerobic digestion method. It was revealed that vermicomposting and BSFL were on par with anaerobic digestion for carbon recovery, nitrogen recovery and mass reduction. Thermophilic anaerobic digestion was found superior in pathogen destruction because of its high operational temperature. Anaerobic digestion also had proven its ability to stabilize heavy metals, but no conclusive finding could confirm similar application from vermicomposting or BSFL treatment. However, the addition of co-substrates or biochar during vermicomposting or BSFL treatment may show synergistic effects in stabilizing heavy metals as demonstrated by anaerobic digestion. Moreover, vermicomposting and BSFL valorization had manifested their potentialities as the low-cost alternatives for treating hazardous sewage sludge, whilst producing value-added feedstock for biochemical industries.